School of Materials Science and Engineering,Harbin Institute of Technology
采用熔盐法以五水硝酸铋为铋源,硒粉为硒源,水合肼作为还原剂在不同NaOH浓度下(0-3mol/L)合成了Bi2O2Se纳米片,并采用XRD、SEM、TEM以及XPS等对样品的形貌、结构和成分进行了表征。然后,以Bi2O2Se为工作电极制备了宽光谱自供能探测器,并探究了它们的光电探测性能。测试结果表明,在1.1mol/L NaOH的条件下,Bi2O2Se自供能探测器的光电探测性最优。在紫外-可见-红外波段,具有较高的响应。在365 nm紫外光照射下,光电流最高可以达到7.8 μA,其上升和下降时间分别为30 ms和21 ms,同时通过计算可以得到其响应度和探测率分别为4.2×10-4A/W和1.02×109Jones。
Bi2O2Se nanosheets were synthesized by molten salt method using Bismuth nitrate pentahydrate as bismuth source, selenium powder as selenium source and hydrazine hydrate as reducing agent at different concentrations of NaOH (0-3mol/L). The morphology, structure and composition of the samples were characterized by XRD, SEM, TEM and XPS.SThen, a wide spectrum self-powered detector was prepared using Bi2O2Se as the working electrode, and their photoelectric detection performance was investigated.SThe test results show that the Bi2O2Se self-powered detector has the best photoelectric detection performance under the condition of 1.1mol/L NaOH.SIn the UV-Vis-IR band, it has a high response.SUnder 365nm UV light, the photocurrent can reach 7.8μA, and the rise and fall time are 30ms and 21ms, respectively. The responsivity and detectivity are 4.2×10-4A/W and 1.02×109Jones, respectively.